Synthesis and study of thermal stability of 3-nitro-1,2,4-triazole N-nitroxy-and N-azidomethyl derivatives.

Autor:	Tselinskii, I. V., Tolstyakov, V. V., Putis, S. M., Mel'nikova, S. F.
Předmět:	TRIAZOLES CHEMICAL reactions METHANOL NITRATION NUCLEOPHILIC reactions
Zdroj:	Russian Chemical Bulletin; Nov2009, Vol. 58 Issue 11, p2356-2361, 6p, 1 Graph
Abstrakt:	method for the preparation of new 3-nitro-1,2,4-triazole derivatives has been suggested based on modification of the N-hydroxymethyl group by nitration and nucleophilic substitution reactions. Thermal stability of 3-nitro-1,2,4-triazole N-nitroxy- and N-azidomethyl derivatives, as well as of dinitrates, 5,5′-dinitro-2,2 ′-bisnitroxymethyl-2 H,2′ H-3,3 ′-bi(1,2,4-triazole) and -(nitromethylene)bis(1,2,4-triazole), has been studied. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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