First Enantioselective Total Synthesis of the Reported Structure of (R)-(+)-Orizaterpenyl Benzoate Using an Asymmetric Allylation of a Prochiral Ketone in a Domino Process.

Autor: Tietze, Lutz
Předmět:
Zdroj: Synlett; Sep2010, Vol. 2010 Issue 14, p2130-2132, 3p
Abstrakt: An efficient synthesis of ( R)-orizaterpenyl benzoate ?using a multicomponent domino allylation reaction of a prochiral ketone with allyltrimethyl silane and the enantiopure silyl ether of benzyl phenyl carbinol in the presence of catalytic amounts of TfOH is described. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index