| Autor: |
Shukla, V.A., Shroff, J.J., Srivastava, H.C. |
| Zdroj: |
Textile Research Journal; May1973, Vol. 43 Issue 5, p300-305, 6p |
| Abstrakt: |
Methylolation of acid amides containing various electron-releasing and electron-withdrawing substituents has been carried out with formaldehyde in the presence of sodium hydroxide at pH 10 and at 55°C. The methylolation relative rates and extents of these acid amides have been studied. The results indicate that a number of factors, such as inductive effect, hyperconjugation, stereochemistry, and solvation, govern the rate and extent of methylolation. It was observed that methylol derivatives of acid amides with electron-withdrawing substituents tend to polymerize during methylolation. Methylolation of acid amides containing electron-releasing substituents proceeds better in the presence of triethylamine as compared to sodium hydroxide. [ABSTRACT FROM PUBLISHER] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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