Synthesis, structures and properties of biferrocenyl- and ruthenocenyl-substituted diphosphenesDedicated to the late Professor Pascal Le Floch. This article is part of a themed issue on Main Group chemistry.Electronic supplementary information (ESI) available: Synthetic procedures and spectral data of biferrocenyldichlorophosphine 10and ruthenocenyldichlorophosphine 11. CCDC reference numbers 762039and 762040. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0nj00062k

Autor: Sasamori, Takahiro, Hori, Akimi, Kaneko, Yoshikazu, Tokitoh, Norihiro
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Zdroj: New Journal of Chemistry; Aug2010, Vol. 34 Issue 8, p1560-1564, 5p
Abstrakt: Biferrocenyl and ruthenocenyl diphosphenes were synthesized in a stable crystalline form as new members of a family of d-π systems containing heavier main group elements. Their structures and redox behavior were revealed using X-ray crystallographic analysis and cyclic voltammetry. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index