Crystal structure and thermal stability of Ni151.5Pb24S92. Search for selenium- and tellurium-containing analogs.

Autor: Baranov, A., Isaeva, A., Popovkin, B., Shpanchenko, R.
Zdroj: Russian Chemical Bulletin; Dec2002, Vol. 51 Issue 12, p2139-2144, 6p
Abstrakt: The crystal structure of the subvalent nickel—lead sulfide, which has been described previously as Ni60Pb9S31, was established and the composition of this sulfide was refined based on powder X-ray diffraction data. The true Ni151.5Pb24S92 composition of this compound was confirmed by the EDX techniques. The temperature range of stability of this compound (490—578 °C) was refined by differential thermal analysis. In the search for analogs, the triangulation of the Ni—Pb—Se and Ni—Pb—Te systems at 540 °C was carried out for the first time. No new ternary phases were detected. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index