Electrochemical oxidation of 2H-imidazole N-oxides.

Autor: Irtegova, I., Starichenko, V., Kirilyuk, I., Grigor"ev, I.
Zdroj: Russian Chemical Bulletin; Nov2002, Vol. 51 Issue 11, p2065-2069, 5p
Abstrakt: Electrochemical oxidation of 2 H-imidazole N-oxides was studied using cyclic voltammetry and ESR spectroscopy. The formation of the 2,2-dimethyl-4,5-diphenyl-2 H-imidazole 1,3-dioxide radical cation was noticed for the first time. The possibility of reaction between the 2 H-imidazole N, N-dioxide radical cation and methanol including the detachment of a hydrogen atom from the MeOH methyl group was demonstrated. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index