| Autor: |
Yakupov, M., Shereshovets, V., Imashev, U., Ismagilov, F. |
| Zdroj: |
Russian Chemical Bulletin; Dec2001, Vol. 50 Issue 12, p2352-2355, 4p |
| Abstrakt: |
The products and kinetics of the liquid-phase oxidation of 11 aliphatic and aromatic thiols with chlorine dioxide were studied at –10—+70 °C in organic media. The rate constants and activation parameters of the reaction were determined. The influence of the thiol structure on its reactivity was studied. A strong solvent effect on the reaction rate constant was found, and the reaction mechanism was proposed. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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