Reactivity indices of adamantane-containing diamines in the synthesis of polyimides.

Autor: Novakov, I., Orlinson, B., Kuznechikov, O., Kulago, I., Pavlyuchko, A., Sabirov, Z., Urazbaev, V., Monakov, Yu.
Zdroj: Russian Chemical Bulletin; Feb1999, Vol. 48 Issue 2, p282-284, 3p
Abstrakt: The reactivity of adamantane-containing diamines in the reactions with dianhydrides of 3,4,3′, 4′-tetracarboxydiphenyl oxide was studied as a function of the parameters of their electronic structures. It was found that the reactivity changes in parallel with the charges on the N atoms, the energy of homolytic cleavage of the N-H bond, and the basicity of diamines. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index