Crystal Structures of Dibenzo-13-crown-4 and sym-(2-Picolyloxy)dibenzo-13-crown-4.

Autor: Dalley, N., Olsher, Uriel, Kou, Xiaolan, Bartsch, Richard, Lee, Jong
Zdroj: Journal of Inclusion Phenomena & Molecular Recognition in Chemistry; Nov1997, Vol. 29 Issue 3/4, p309-321, 13p
Abstrakt: Solid-state structures are determined for two compounds which containdibenzo-13-crown-4 rings. These include the parent crown etherdibenzo-13-crown-4 and its lariat ether derivativesym-(2-picolyloxy)dibenzo-13-crown-4. The solid-state structure ofdibenzo-13-crown-4 is complicated by disorder of the carbon atoms in theethylene and propylene bridges. The asymmetric unit of the crystal for thelariat ether derivative consists of two chemically identical, butcrystallographically different, molecules. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index