Calorimetric Effects of Simple Ion Adsorption at the Oxide-Electrolyte Interfaces: Seeking for a Simple Interpretation of the Data Obtained by Titration Calorimetry.

Autor: Rudziński, W., Charmas, R., Piasecki, W., Kallay, N., Cases, J.M., François, M., Villieras, F., Michot, L.J.
Zdroj: Adsorption; Sep1998, Vol. 4 Issue 3/4, p287-297, 11p
Abstrakt: The theoretical description of the enthalpic effects accompanying ion adsorption at the oxide-electrolyte interface, developed recently by Rudzinski and co-workers, is used here to analyze the Kallay's experimental procedure of determining nonconfigurational heats of proton adsorption in a simple experiment involving use of titration calorimetry. That theoretical analysis, based on considering a certain real adsorption system, leads to important recommendation at which conditions the Kallay's titration experiment yields the most reliable figures describing the heats of proton adsorption. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
Externí odkaz: