Mechanism of the Oxidation of Lower Aliphatic Alcohols with Catalysis by Giant Pd-561 Clusters.

Autor: Starchevskii, M., Gladii, S., Pazderskii, Yu., Vargaftik, M., Moiseev, I.
Zdroj: Theoretical & Experimental Chemistry; Nov2000, Vol. 36 Issue 6, p312-318, 7p
Abstrakt: The mechanism of oxidation of lower aliphatic alcohols by oxygen in solutions of giant Pd-561 clusters was examined. The mechanism involves the formation of two types of intermediate particles on the surface of the metal cluster. Their further transformations involve interaction with the external substrates. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index