| Autor: |
Kotseruba, V., Chikhichin, D., Kamalov, G., Gérbéléu, N., Timko, G., Synzheryan, L. |
| Zdroj: |
Theoretical & Experimental Chemistry; May1999, Vol. 35 Issue 3, p172-178, 7p |
| Abstrakt: |
On the basis of a comparison of the rates of formation of the hydroperoxide, benzaldehyde, and benzoic acid—the basic products of the liquid-phase oxidation of dibenzyl ether in the presence of complexes with the composition Cr2MOPiv6·3L (M=Cr(III), Fe(III), Ni(II), Co(II); L=PPy, γ-Pic, H2O)—it was concluded that, when the sequence of reactions dibenzyl ether→hydroperoxide→benzaldehyde has occurred to a small extent, activation of the substrates occurs at the same catalytic center. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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