Oxidizing Reactions of Azines. 7. Imination of 4-Aryl-1,2,3,6-tetrahydropyridines by Arylamines in the Presence of Potassium Permanganate. Molecular Structure of 1-Methyl-2-(4-nitrophenylimino)-4-phenyl-1,2,5,6-tetrahydropyridine.

Autor: Soldatenkov, A., Khristoforova, T., Temesgen, A., Anissimov, B., Averkiev, B., Kuleshova, L., Khrustalev, V., Antipin, M.
Zdroj: Chemistry of Heterocyclic Compounds; Jun2001, Vol. 37 Issue 6, p715-722, 8p
Abstrakt: On treating 4-aryl substituted 1-methyl-1,2,3,6-tetrahydropyridines with potassium permanganate in the presence of arylamines a previously unknown intermolecular oxidative imination reaction occurs leading to the formation of 2-(arylimino)-1,2,5,6-tetrahydropyridines. The molecular structure of 1-methyl-2-(4-nitrophenylimino)-4-phenyl-1,2,5,6-tetrahydropyridine was studied by X-ray analysis and it was shown that the hydropyridine ring of the molecule has a sofa conformation and its amidine fragment is in the E-configuration. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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