Synthesis of 2,5-bis(2-aminothiazol-5-yl)-3,6-dichloro-1,4-benzoquinones.

Autor: Batenko, N., Valters, R., Karlivans, G.
Zdroj: Chemistry of Heterocyclic Compounds; Jun2000, Vol. 36 Issue 6, p733-737, 5p
Abstrakt: A series of 2-(2-aminothiazol-5-yl)-3,6-dichloro-5-diethylaminoethenyl-1,4-benzoquinones was synthesized from 2-(2-aminothiazol-5-yl)-3,5,6-trichloro-1,4-benzoquinones using acetaldehyde and diethylamine in toluene solution. Refluxing these compounds with substituted thioureas in acetonitrile in the presence of hydrochloric acid gives the corresponding 2,5-bis(2-aminothiazol-5-yl)-3,6-dichlorohydroquinones which can be oxidized to the target products with ferric chloride in aqueous DMF. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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