Photochemical oxidation of 4h-seleno(thio)pyrans.

Autor: Drevko, B., Fomenko, L., Suchkov, M., Kharchenko, V.
Zdroj: Chemistry of Heterocyclic Compounds; Jun1999, Vol. 35 Issue 6, p663-665, 3p
Abstrakt: Oxidation of solutions of 4H-thiopyrans and 4H-selenopyrans to the corresponding heteroaromatic cation bromide occurs on irradiation with ultraviolet light in the presence of CBr4. Reaction takes place by a free radical chain mechanism. The presence of CHBr3 and C2Br6 in the reaction mixture was detected chromatographically. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index