Reaction of Grignard Compounds with 4-Chloro-2-methyl-3-butyn-2-ol in Diethyl Ether Equivalents.

Autor: Shchelkunov, S., Sivolobova, O., Mataeva, S., Minbaev, D., Muldakhmetov, Z.
Zdroj: Russian Journal of Organic Chemistry; Jan2001, Vol. 37 Issue 1, p5-8, 4p
Abstrakt: Reactions of RMgX·THF complexes with 4-chloro-2-methyl-3-butyn-2-ol in aromatic hydrocarbons were studied. The complexes formed by arylmagnesium halides require the presence of anisole for the reaction to occur. 4-Chloro-2-methyl-3-butyn-2-ol can be synthesized by reaction of 2-methyl-3-butyn-2-ol with sodium hypochloride in the two-phase system water-benzene. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index