Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: IV.1 Features of the Reaction of 2,2,2,4,5,6,7-Heptachlorobenzo[d]-1,3,2λ5-dioxaphosphole with Phenylacetylene. Molecular and Supramolecular Structure of 2-Oxo-4-phenyl-2,5,6,7,8-pentachlorobenzo[e]-1,2λ5(2H)-oxaphosphorine and Its Hydrolysis Products

Autor: Mironov, V., Gubaidullin, A., Shtyrlina, A., Litvinov, I., Petrov, R., Konovalov', A., Dobrynin, A., Zyablikova, T., Musin, R., Morozov, V.
Zdroj: Russian Journal of General Chemistry; Nov2002, Vol. 72 Issue 11, p1764-1783, 20p
Abstrakt: As shown by NMR and IR spectroscopy and high-resolution mass spectrometry, the major products of the reaction of 2,2,2,4,5,6,7-heptachlorobenzo[ d]-1,3,2λ5-dioxaphosphole with phenylacetylene are a six-membered heterocyclic compound, 2-oxo-4-phenyl-2,5,6,7,8-pentachlorobenzo[ e]-1,2λ5(2 H)-oxaphosphorine, and the E and Z isomers of 2-(2,3,4,4,5-pentachlorocyclohexadienon-6-yl)-2-phenylvinylphosphonic dichloride. The molecular and supramolecular structure of the heterocycle and phosphorus-containing products of its hydrolysis were studied by single crystal X-ray diffraction. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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