Methyl Trifluoropyruvate Diethoxyphosphorylimine.

Autor: Onys'ko, P., Rassukanaya, Yu., Sinitsa, A.
Zdroj: Russian Journal of General Chemistry; Nov2002, Vol. 72 Issue 11, p1699-1702, 4p
Abstrakt: The first example of trifluoropyruvate phosphorylimines was prepared, and its capability for O- and S-amidoalkylation of water, alcohols, and compounds with the SH function was shown. Phenol and 4-methoxyphenol are O-alkylated, while 3-dimethylaminophenol and indole undergo regiospecific C-alkylation at the site of the highest π-electron density. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index