| Autor: |
Jungbluth, Achim, Kolloch, Michael, Marx, F., Pfeilsticker, Konrad |
| Zdroj: |
Zeitschrift für Lebensmitteluntersuchung und -forschung A; Mar1997, Vol. 204 Issue 3, p215-220, 6p |
| Abstrakt: |
The initial steps of the degradation of L-de- hydroascorbic acid ( L-DHA) in acidic aqueous solutions and the catalytic effect of different transition metal ions on this reaction were studied. The main product was identified as 3,6-furanosido-2,3-hexodiulosonic acid-2-hydrate (compound I) by GLC-MS and 13C-NMR, formed by lactone hydrolysis and hydration of the carbonyl group in the C-2 position of L-dehydroascorbic acid. In addition, number of other compounds were detected; they are formed from compound I by simple enolisation, lactonisation, hydration and dehydration reactions as well as by cleavage and formation of cyclic half acetal bonds. The chemical structures of these compounds were tentatively deduced by the mass spectra of their TMS derivatives and a reaction scheme for their formation is proposed. The velocity and the direction of the reactions were found to be strongly influenced by the presence of catalytic amounts of different transition metal ions. It was concluded that in acidic medium, in contrast to the situation in neutral and alkaline solutions, the opening of the lactone ring of L-DHA is, to a certain degree, a reversible reaction. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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