Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding.

Autor: Bridget Williams, D., Kaminsky, Werner, Mayer, James M., Goldberg, Karen I.
Předmět:
Zdroj: Chemical Communications; Sep2008, Vol. 2008 Issue 35, p4195-4197, 3p
Abstrakt: The reaction of molecular oxygen with iridium pincer hydride complexes, (tBuPCP)Ir(H)(X) [tBuPCP = κ3-C6H3(CH2PtBu2)2, X = Ph, H, CCPh], results in O2 induced reductive elimination and formation of the novel dioxygen complexes (tBuPCP)Ir(O2)n [n = 1 (7), 2 (6)]. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index