Autor: |
Brun, Sandra, Garcia, Lídia, González, Iván, Torrent, Anna, Dachs, Anna, Pla-Quintana, Anna, Parella, Teodor, Roglans, Anna |
Předmět: |
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Zdroj: |
Chemical Communications; Sep2008, Vol. 2008 Issue 36, p4339-4341, 3p |
Abstrakt: |
A series of fused tetracycles with a benzene or cyclohexadiene core (2a–h) is satisfactorily prepared by intramolecular [2 + 2 + 2] cycloadditions of triynic and enediynic macrocycles (1a–h) under RhCl(PPh3)3 catalysis; the enantioselective cycloaddition of macrocycles 1b and 1e gives chiral tetracycles with moderate enantiomeric excess. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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