Modulating the luminescence of an iridium(iii) complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand with Zn2+cationsElectronic supplementary information (ESI) available: Full experimental procedures, photophysical data and UV-vis titrations, details of the X-ray structure of 1. CCDC reference number 718415. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b9nj00515c.

Autor: Araya, Juan C., Gajardo, Juana, Moya, Sergio A., Aguirre, Pedro, Toupet, Loïc, Williams, J. A. Gareth, Escadeillas, Muriel, Le Bozec, Hubert, Guerchais, Véronique
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Zdroj: New Journal of Chemistry; Jan2010, Vol. 34 Issue 1, p21-24, 4p
Abstrakt: A novel iridium complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand was synthesized and its optical properties studied. The presence of Zn2+ions specifically perturbs the excited state, giving rise to a blue-shifted absorption and emission, and a shorter luminescence lifetime. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index