The unusual self-organising behaviour of a glycosteroidal bolaphileElectronic supplementary information (ESI) available: Experimental details and characterization data. See DOI: 10.1039/b908235b.

Autor: Fahima Ali Rachedi, Stéphane Chambert, Fouad Ferkous, Yves Queneau, Stephen J. Cowling, John W. Goodby
Předmět:
Zdroj: Chemical Communications; Nov2009, Vol. 2009 Issue 42, p6355-6357, 3p
Abstrakt: In this communication we report on the self-organising properties of a novel asymmetric bolaphile composed of sugar and steroidal units. The material was found to exhibit unusual phase changes in that it formed a cubic phase upon heating, whereas upon cooling it formed a lamellar phase. This change in property was ascribed to kinetic versusthermodynamic behaviour at the phase transition to the liquid. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index