| Autor: |
Feldman, Vladimir I., Kobzarenko, Alexey V., Baranova, Irina A., Danchenko, Alexander V., Sukhov, Fedor F., Tsivion, Ehud, Gerber, R. Benny |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 10/21/2009, Vol. 131 Issue 15, p151101, 3p, 1 Chart, 1 Graph |
| Abstrakt: |
IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes (129Xe and 136Xe) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H–Xe stretching (by 0.17–0.38 cm-1). To our knowledge, it is the first direct experimental evidence for the H–Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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