Deuterium-induced degradation of (Ba, Sr)TiO[sub 3] films.

Autor: Ahn, Joon-Hyung, McIntyre, Paul C., Mirkarimi, Laura Wills, Gilbert, Stephen R., Amano, Jun, Schulberg, Michelle
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Zdroj: Applied Physics Letters; 8/28/2000, Vol. 77 Issue 9
Abstrakt: Electrical degradation of (Ba, Sr)TiO[sub 3] (BST) thin films was investigated by annealing Pt/BST/Pt structures in D[sub 2]/N[sub 2] and D[sub 2]O-containing furnace ambients. Deuterium depth profiles were correlated to the current-voltage characteristics of the BST thin films. The dependence of the D distribution and leakage current density on the D incorporation method indicates that mobile, donor-type deuterium defects dissolve in large concentrations within BST thin films, and that their effects on leakage properties depend on the nature of their charge compensation. A mechanism is proposed for the leakage current increase after D[sub 2]/N[sub 2] anneals, and good quantitative agreement between the theoretical results and experimental data is demonstrated. © 2000 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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