Experimental investigation of the 85Rb2 a 3Σu+ triplet ground state: Multiparameter Morse long range potential analysis.

Autor: Beser, Bediha, Sovkov, V. B., Bai, J., Ahmed, E. H., Tsai, C. C., Xie, F., Li, Li, Ivanov, V. S., Lyyra, A. M.
Předmět:
Zdroj: Journal of Chemical Physics; 9/7/2009, Vol. 131 Issue 9, p094505, 6p, 1 Diagram, 4 Charts, 5 Graphs
Abstrakt: Using perturbation facilitated infrared-infrared double resonance excitation of the 85Rb2 molecule, we have observed spectrally resolved fluorescence to the a 3Σu+ state. We have analyzed the rovibrational energy level structure of the 85Rb2 a 3Σu+ state and derived a multiparameter Morse Long Range (MLR) potential and molecular constants for this state, which can be used to predict term values without needing to solve the radial Schrödinger equation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index