The Isolation of a Large Cyclopentadienylcobaltsulfide Cluster. The Synthesis and Crystal Structure of Octahedral closo-(η5-C5H5Co)5S.

Autor:	Ryan Holland, Joseph O’Connor, Arnold Rheingold
Předmět:	SEPARATION (Technology) SULFONES ORGANIC synthesis COBALT sulfide CRYSTALS MOLECULAR structure MICROCLUSTERS
Zdroj:	Journal of Cluster Science; Jun2009, Vol. 20 Issue 2, p261-265, 5p
Abstrakt:	Abstract  The title cluster, which was obtained serendipitously when (η5-C5H5)Co(PPh3)2 was added to a (η5-C5H5)Co metallacyclobutene containing a sulfone group, is the largest cluster known, formed primarily with (η5-C5H5)Co vertices. The closo-(η5-C5H5Co)5S is a closed-shell, octahedral cluster which forms black, monoclinic crystals from methanol. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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