Intramolecular energy transfer in highly vibrationally excited methanol. I. Ultrafast dynamics.

Autor: Boyarkin, O.V., Lubich, L., Settle, R.D.F., Perry, D.S., Rizzo, T.R.
Předmět:
Zdroj: Journal of Chemical Physics; 11/22/1997, Vol. 107 Issue 20, p8409, 14p, 3 Diagrams, 2 Charts, 6 Graphs
Abstrakt: Part I. Discusses the intramolecular energy transfer in highly vibrationally excited jet-cooled methanol. Observation of spectral splitting; Identifying the perturbing state as combination level involving four quanta of hydroxide stretch and one quantum of methane asymmetric stretch.
Databáze: Complementary Index