Equilibrium properties of the solvated electron in polar liquids: Finite solvent size effects.

Autor: Rips, Ilya, Tachiya, Masanori
Předmět:
Zdroj: Journal of Chemical Physics; 9/8/1997, Vol. 107 Issue 10, p3924, 6p, 1 Chart, 4 Graphs
Abstrakt: Discusses a microscopic theory of a solvated electron in simple polar liquid. Application of the Pekar-Frohlich variational approach for the finite size of the solvent molecules; Localization of solvated electron within the cavity create in the solvent; Total energy of the localized electron in the solvent of polarizable hard spheres.
Databáze: Complementary Index