Binding energies of palladium carbonyl cluster anions: Collision-induced dissociation of....

Autor: Spasov, Vassil A., Ervin, Kent M.
Předmět:
Zdroj: Journal of Chemical Physics; 10/1/1998, Vol. 109 Issue 13, p5344, 7p, 1 Diagram, 3 Charts, 3 Graphs
Abstrakt: Examines the gas-phase palladium trimer anion and carbonyls by the collision-induced dissociation method. Importance of the bond energies of carbonyls on palladium clusters; Decrease of bond energy with increasing number of carbonyls; Hypothesis of a symmetric Pd3(CO)-2 structure with two three-fold bridged carbonyls.
Databáze: Complementary Index