The Preparation, Characterization and X-ray Structural Analysis of Tetrakis[1-Methyl-3-(2-Propyl)-2(3H)-Imidazolethione]Cadmium(II) Hexafluorophosphate.

Autor: Daniel Williams, Daniel Gulla, Kimberly Arrowood, Lindsey Bloodworth, Angela Carmack, Taylor Evers, Mark Wilson, Javier Concepcion, Carol Brevett, Benjamin Huck, Donald VanDerveer
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Zdroj: Journal of Chemical Crystallography; Aug2009, Vol. 39 Issue 8, p581-584, 4p
Abstrakt: Abstract  A new compound, [Cd(mipit)4][PF6]2 has been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography (mipit = 1-methyl-3-(2-propyl)-2(3H)-imidazolethione). The title compound crystallizes in tetragonal space group I4 1 /a with a = 12.478(2) Å, b = 12.478(2) Å, c = 28.806(6) Å, and Z = 4. The complex is a high melting, colorless solid that has a distorted tetrahedral CdS4 coordination geometry. Thermogravimetric analysis results for the title compound as well as for another potential CdS synthon and two potential CdSe synthons are reported. Graphical Abstract  The synthesis and characterization of the title compound, a new ionic homoleptic cadmium complex, tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]cadmium(II) hexafluorophosphate is reported. The results of a single crystal X-ray diffraction analysis reveal a distorted tetrahedral CdS4 coordination sphere about the cadmium. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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