An unprecedented all helical 3D network and a rarely observed non-interpenetrated octahedral network in homochiral Cu(II) MOFs: effect of steric bulk and π–π stacking interactions of the ligand backboneElectronic supplementary information (ESI) available: Schemes S1–S2, Figures S1–S2 and TGA. CCDC reference numbers 699625 and 699626. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b820087b

Autor:	Subhabrata Banerjee, N. N. Adarsh, Parthasarathi Dastidar
Předmět:	MIXED oxide fuels (Nuclear engineering) COPPER CHIRALITY LIGANDS (Chemistry) AMINO acids MOLECULAR structure SUPRAMOLECULAR chemistry
Zdroj:	CrystEngComm; May2009, Vol. 11 Issue 5, p746-749, 4p
Abstrakt:	Two bis-pyridyl-bis-amide based chiral ligands derived from L-phenylalanine and L-alanine resulted in an unprecedented all helical 3D network and a rarely observed microporous octahedral network in the corresponding homochiral Cu(II) MOFs. This remarkable structural difference displays the effect of amino acid side chain and ligating topology of the ligands on the supramolecular structures in these MOFs. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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