Complementary Reactions of Allylic Carbamates Using Palladium(II): Formation of Oxazolidinones or Allylic Amides from a Common Precursor.
| Autor: | Steven Christie |
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| Zdroj: | Synthesis; Jan2009, Vol. 2009 Issue 1, p148-154, 7p |
| Abstrakt: | The use of palladium to effect two different reactions on a common starting material is presented. With a copper oxidant, an aminohalogenation is achieved to produce oxazolidinones. When the copper is absent, a [3,3]-sigmatropic rearrangement takes place to produce allylic amides. [ABSTRACT FROM AUTHOR] |
| Databáze: | Complementary Index |
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