Cyanide 13C NMR hyperfine shifts in paramagnetic cyanide-bridged mixed-valence complexes.

Autor: W. Michael Laidlaw, Robert G. Denning
Předmět:
Zdroj: Chemical Communications; Mar2008, Vol. 2008 Issue 13, p1590-1592, 3p
Abstrakt: Paramagnetic (hyperfine) NMR shifts in the 13C cyanide bridge and 31P resonances in a set of mixed valence complexes [(η5-C5R5)Ru(PPh3)L(13CN)Ru(NH3)5]n+ (R = H; L = PPh3, CO, NO+; R = Me; L = PPh3) are sensitive to the extent of intermetallic charge-transfer, and are strongly solvent dependent. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index