Effects of Temperature Gradients and Heat Fluxes on High-Temperature Oxidation.

Autor: Gordon Holcomb
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Zdroj: Oxidation of Metals; Apr2008, Vol. 69 Issue 3/4, p181-192, 12p
Abstrakt: Abstract  The effects of a temperature gradient and heat flux on point defect diffusion in protective oxide scales were examined. Irreversible thermodynamics were used to expand Fick’s first law of diffusion to include a heat-flux term—a Soret effect. Oxidation kinetics were developed for the oxidation of cobalt and of nickel doped with chromium. Research is described to verify the effects of a heat flux by oxidizing pure cobalt in a temperature gradient at 900 °C, and comparing the kinetics to isothermal oxidation. No evidence of a heat flux effect was found. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index