| Autor: |
Jacobs, D. T., Braganza, Clinton I., Brinck, Andy P., Cohen, Adam B., Lightfoot, Mark A., Locke, Christopher J., Suddendorf, Sarah J., Timmers, Henry R., Triplett, Angela L., Venkataraman, Nithya L., Wellons, Mark T. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 9/28/2007, Vol. 127 Issue 12, p124905, 10p, 2 Charts, 11 Graphs |
| Abstrakt: |
Measurements of the coexistence curve and turbidity were made on different molecular mass samples of the branched polymer-solvent system eight-arm star polystyrene in methylcyclohexane near its critical point. We confirmed that these systems belong in the Ising universality class. The location of the critical temperature and composition as well as the correlation length, susceptibility, and coexistence curve amplitudes were found to depend on molecular mass and the degree of branching. The coexistence curve diameter had an asymmetry that followed a “complete scaling” approach. All the coexistence curve data could be scaled onto a common curve with one adjustable parameter. We found the coexistence curve amplitude to be about 12% larger for branched than linear polystyrenes of the same molecular mass in either solvent cyclohexane or methylcyclohexane. The two-scale-factor universality ratio R was found to be independent of molecular mass or degree of branching. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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