Hydrogen-adsorption Properties of a Novel Lantern-type Dinuclear Co(BDC)(DABCO)1/2.

Autor: Takei, Tohru, Ii, Takato, Kawashima, Jiro, Ohmura, Tetsushi, Ichikawa, Masao, Hosoe, Mitsuya, Shinya, Yoshiaki, Kanoya, Izuru, Mori, Wasuke
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Zdroj: Chemistry Letters; 9/5/2007, Vol. 36 Issue 9, p1136-1137, 2p, 1 Diagram, 2 Graphs
Abstrakt: A three-dimensional (3-D) cobalt coordination polymer Co(BDC)(DABCO)½ (BDC = 1,4-benzenedicarboxylate; DABCO = 1,4-diazabicyclo[2.2.2]octane), which has a novel lantern-type structure, was synthesized and characterized by X-ray powder diffraction patterns and elemental analysis. In addition, hydrogen-adsorption characteristics were evaluated at 77 K. The highest measured hydrogen uptake was 2.28 wt% at 77K and 0.1 MPa for Co(BDC)(DABCO)½. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index