Dissociative recombination study of N3+: Cross section and branching fraction measurements.

Autor: Zhaunerchyk, V., Geppert, W. D., Vigren, E., Hamberg, M., Danielsson, M., Larsson, M., Thomas, R. D., Kaminska, M., Österdahl, F.
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Zdroj: Journal of Chemical Physics; 7/7/2007, Vol. 127 Issue 1, p014305, 5p, 2 Graphs
Abstrakt: We report an investigation into the dissociative recombination of the azide radical cation, N3+. The reaction rate constant has been measured to be 6.47×10-7 cm3 s-1 at room temperature. This value is smaller than those reported earlier for the ion-electron neutralization of N3+ at nitrogen atmospheric pressure. A strong propensity to dissociate through the N2+N channel has been observed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index