Liquid-crystalline behaviour in the n-alkyl gluconamides and other related carbohydrates.

Autor: Pfannemüller, B., Welte, W., Chin, E., Goodby, J. W.
Předmět:
Zdroj: Liquid Crystals; Nov/Dec2006, Vol. 33 Issue 11/12, p1238-1245, 8p, 6 Black and White Photographs, 1 Diagram, 2 Charts, 8 Graphs
Abstrakt: Many alkyl derivatives of carbohydrates are used as detergents for cell wall membranes. This study describes the liquid-crystalline properties of a number of these systems. The combination of a hydrophilic carbohydrate moiety and a hydrophobic aliphatic substituent leads to the formation of both thermotropic and lyotropic liquid-crystal mesophases. Materials with this structural combination are suspected to form interdigitated bilayer smectic A phases. The central core region of the layer is held together by dynamic hydrogenbonding between the neighbouring carbohydrate moieties, whereas the terminal aliphatic chains create fluidity between layers. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index