Metallophilic interactions in iodido(2,2′:6′,2′′-terpyridine)platinum(II) diiodidoaurate(I).

Autor: Angle, Christina S., Woolard, Kathryn J., Kahn, Michael I., Golen, James A., Rheingold, Arnold L., Doerrer, Linda H.
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Zdroj: Acta Crystallographica: Section C (Wiley-Blackwell); Jun2007, Vol. 63 Issue 6, pm231-m234, 1p, 4 Diagrams
Abstrakt: In the title compound, [PtI(C15H11N3)][AuI2], the [PtI(terpy)]+ cations (terpy is 2,2′:6′,2′′-terpyridine) stack in pairs about inversion centers through Pt...Pt interactions of 3.5279 (5) Å. The [AuI2] anions also exhibit pairwise stacking, with Au...I distances of 3.7713 (5) Å. The [PtI(terpy)]+ cations and [AuI2] anions aggregate forming infinite arrays of stacked ...({[PtI(terpy)]+...[PtI(terpy)]+}...{[AuI2]...[AuI2]})... units. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index