Fabrication of epitaxial III-nitride cantilevers on silicon (1 1 1) substrates.

Autor: S. Davies, T. S. Huang, R. T. Murray, M. H. Gass, A. J. Papworth, T. B. Joyce, P. R. Chalker
Zdroj: Journal of Materials Science: Materials in Electronics; Nov2004, Vol. 15 Issue 11, p705-710, 6p
Abstrakt: The molecular beam epitaxy of AlGaN/GaN epilayers on silicon (1 1 1) using an aluminum nitride buffer layer, and subsequent fabrication of free standing III-nitride cantilevers on Si(1 1 1) has been investigated. Transmission electron microscopy (TEM) of cross-section samples reveals a columnar structure consisting of the hexagonal gallium nitride polytype. Selected area diffraction indicates an epitaxial relationship between the gallium nitride and silicon substrate which is described by GaN[0 0 0 1]//Si[1 1 1] and GaN(1 1 0 0)//Si(1 1 1). Imaging of the electronic structure of an AlGaN/GaN interface has been investigated by mapping the variation in the plasmon frequency using an electron energy loss spectrometer on a dedicated scanning transmission electron microscope. Cantilevers were fabricated using a combination of etching processes. Nitride etch rates during inductively coupled plasma dry etch processing using a Cl 2 /Ar plasma etchant were obtained by monitoring the optical reflectivity of the nitride films in situ. A peak GaN etch rate of 250 nm/min was measured, the etch rate was found to be strongly dependent on the d.c. self-bias. Thin beams of GaN having a length of 7 µm and 0.7 µm thickness, were fabricated and mechanically released from Si(1 1 1) substrates using a combination of two dry ICP etch processes, using Cl 2 /Ar and CF 4 /Ar/O 2 chemistries, and a potassium hydroxide (KOH) aqueous wet etch. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index