Synthesis and Crystal Structure of a New Copper–PMIDA Compound (H4PMIDA=H2O3PCH2N(CH2CO2H)2).

Autor:	Hongxia Pei, Sheming Lu, Yanxiong Ke, Jianmin Li, Shoubo Qin, Shuxi Zhou
Zdroj:	Structural Chemistry; Jun2004, Vol. 15 Issue 3, p207-210, 4p
Abstrakt:	A new Cu(II)PMIDA compound [Cu(H2PMIDA)(phen)] · 3H2O (1) (H4PMIDA = H2O3PCH2N (CH2CO2H)2,phen = 1,10-phenanthroline) has been successfully synthesized and structurally characterized. In complex 1, Cu (II) is six coordinated by chelation in a tetradentate fashion by a PMIDA ligand and by two N atoms of a phen ligand. Every phen–Cu(II)–PMIDA group connects with each other via a hydrogen bond and the edge-to-face π-stacking interaction. Complex 1 crystallized in triclinic P-1 with cell dimensions of a = 7.5817(6) Å, b = 10.6980(8) Å, c = 13.1852(10) Å, α=82.350(2)°, β = 84.151(2)°, γ=78.4250(2), V= 1035.25(14) Å3, Z = 2, Dc = 1.677 Mg/m3. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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