| Autor: |
V. V. Roznyatovsky, N. E. Borisova, M. D. Reshetova, Yu. A. Ustynyuk, G. G. Aleksandrov, I. L. Eremenko |
| Zdroj: |
Russian Chemical Bulletin; Jun2004, Vol. 53 Issue 6, p1208-1217, 10p |
| Abstrakt: |
New dinuclear complexes containing CuII atoms in the cavity of a macrocyclic Schiff base were prepared by template condensation of 4-tert-butyl-2,6-diformylphenol with 1,3-diaminopropane in the presence of CuII trimethylacetate and chloride as well as by extra-ligand exchange. The mononuclear CuII complex with two 1,3-diaminopropane molecules can serve as an intermediate in this template synthesis. The reaction of CuII trimethylacetate with the unsymmetrical macrocyclic Schiff base synthesized earlier afforded a new dinuclear copper(ii) complex with the amine and imine nitrogen atoms in the coordination sphere. The structures of the new complexes were established by X-ray diffraction analysis and studied by the density functional theory (gradient-corrected PBE functional, TZ2p basis set). [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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