Hydrolytic condensation of trialkoxysilanes in the presence of alkali metal and copper(ii) ions. Influence of the reaction conditions on the structure of Cu/M organosiloxanes.

Autor:	Yu. A. Molodtsova, Yu. A. Pozdnyakova, I. V. Blagodatskikh, A. S. Peregudov, O. I. Shchegolikhina
Zdroj:	Russian Chemical Bulletin; Dec2003, Vol. 52 Issue 12, p2722-2731, 10p
Abstrakt:	The formation of polyhedral copper/sodium(potassium) organosiloxanes was examined as a result of hydrolytic condensation of organotrialkoxysilanes in the presence of copper(ii) and sodium or potassium ions. High selectivity of the synthesis of copper/sodium(potassium) organosiloxanes having desired structures can be achieved by choosing the reaction conditions. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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