Charge transport in melt-dispersed carbon nanotubes.

Autor: Hobbie, E. K., Obrzut, J., Kharchenko, S. B., Grulke, E. A.
Předmět:
Zdroj: Journal of Chemical Physics; 7/28/2006, Vol. 125 Issue 4, p044712, 3p, 4 Graphs
Abstrakt: We investigate the effect of interfacial stabilizer on charge transport in polymer-dispersed carbon nanotubes. Despite mechanical contact, samples with dispersant show poor conductivity, which we attribute to a robust interfacial layer between contacted nanotubes. In comparison, results obtained when nanotubes are mechanically mixed into polymer melts without dispersant show much better conductivity. The difference is striking; at comparable loading, neat melt composites have resistivities five orders of magnitude smaller than those containing interfacial stabilizer. Our results highlight a fundamental issue for the engineering of conducting carbon nanotube composites; dispersion stability will typically be achieved at the expense of conductivity. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index