Large-scale production of carbon-coated copper nanoparticles for sensor applications.

Autor: E K Athanassiou, R N Grass, W J Stark
Předmět:
Zdroj: Nanotechnology; Mar2006, Vol. 17 Issue 6, p1668-1673, 6p
Abstrakt: Copper nanoparticles with a mean carbon coating of about 1nm were continuously produced at up to10gh−1 using amodified flame spray synthesis unit under highly reducing conditions. Raman spectroscopy and solid state13C magicangle spinning nuclear magnetic resonance spectroscopy revealed that the thin carbon layer consistedof a sp2-hybridized carbon modification in the form of graphene stacks. The carbon layer protectedthe copper nanoparticles from oxidation in air. Bulk pills of pressed carbon/coppernanoparticles displayed a highly pressure-and temperature-dependent electricalconductivity with sensitivity at least comparable to commercial materials. These propertiessuggest the use of thin carbon/copper nanocomposites as novel, low-cost sensor materialsand offer a metal-based alternative to the currently used brittle oxidic spinels orperovskites. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index