Structure and photochromism of 2-(N-acyl-N-arylaminomethylene)benzo[b]thiophen-3(2H)-ones.

Autor: A. D. Dubonosov, V. P. Rybalkin, Ya. Yu. Vorob’eva, V. A. Bren’, V. I. Minkin, S. M. Aldoshin, V. V. Tkachev, A. V. Tsukanov
Zdroj: Russian Chemical Bulletin; Oct2004, Vol. 53 Issue 10, p2248-2252, 5p
Abstrakt: Abstract It was shown by electron absorption spectroscopy and X-ray diffraction analysis that steric strains in photochromic 2-(N-acyl-N-arylaminomethylene) benzo[b]thiophen-3(2H)-one molecules ortho-substituted in the N-phenyl ring increase the quantum yield of the N?O photoinduced rearrangement in accord with an increase in the steric constant of the ortho-substituent. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index