| Autor: |
T. Rodyagina, P. Gaman'kov, E. Dmitrieva, I. Chepurnaya, S. Vasil'eva, A. Timonov |
| Zdroj: |
Russian Journal of Electrochemistry; Oct2005, Vol. 41 Issue 10, p1101-1110, 10p |
| Abstrakt: |
This work is devoted to a consideration of methods of electrochemical synthesis of redox polymers poly[M(Schiff)], where “M” is Ni, or Pd and “Schiff” stands for a four-dentate Schiff base, with a controlled distribution of structural elements (stacks) over the electrode's surface for the optimization of the transport of charge-compensating ions, which is the stage that determines the charge transfer rate in the system under consideration. It is shown that the structuring of these polymers on a molecular level by means of a purposeful selection of the composition of the initial compounds and the conditions of synthesis—the potential of formation and the nature of the solvent and supporting electrolyte—makes it possible to a considerable extent accelerate the charge transfer process in the polymers and improve stability of their electrochemical characteristics. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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