Properties of high-lying vibrational states of the molecular ion.

Autor: Munro, James J., Ramanlal, Jayesh, Tennyson, Jonathan, Mussa, Hamse Y.
Předmět:
Zdroj: Molecular Physics; 1/10/2006, Vol. 104 Issue 1, p115-125, 11p, 5 Charts, 5 Graphs
Abstrakt: Calculations are presented for the vibrational states of on a potential with the correct dissociation properties ( Molec. Phys. , 98, 261 (2000)) using both Radau and Jacobi coordinates. This potential is found to support horseshoe states at low to intermediate energies. Near the dissociation limit a new class of long-range states, called asymptotic vibrational states (AVS), is found. These states are similar to those suggested to explain the observed near-dissociation spectrum of . The possible consequences of such states are discussed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index