Autor: |
Miyashita, Yoshitaro, Ohashi, Tetuya, Imai, Akiomi, Amir, Nagina, Fujisawa, Kiyoshi, Okamoto, Ken-ichi |
Předmět: |
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Zdroj: |
Acta Crystallographica: Section C (Wiley-Blackwell); Nov2005, Vol. 61 Issue 11, pm476-m478, 3p |
Abstrakt: |
The complex molecule in the title compound, [Re(C9H6NS)Cl2O(C18H15OP)]·C3H6O, has distorted octahedral geometry. The Re=O bond occupies the position trans to the triphenylphosphine oxide O atom. The Re—Cl bond trans to the thiolate S atom is longer than that trans to the quinoline N atom, implying a stronger trans influence of the S atom. Intra- and intermolecular π–π interactions are also observed between the π rings in the complex. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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